column 7 of the hazardous materials table

136 This entry applies only to articles, machinery, and apparatus containing hazardous materials as an integral element of the article, machinery, or apparatus. TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. B14 Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. (2) A code containing the letter A refers to a special provision which applies only to transportation by aircraft. However, the hazard label corresponding to the hazard class or division may be substituted for the marking. In addition, a container exceeding 4 fluid ounces volumetric capacity (7.22 cubic inches) or containing more than 65 grams of fuel may not be connected or manifolded to a lighter or similar device and must also be described and packaged according to the fuel contained therein. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the 172.101 Table. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. A53 Refrigerating machines and refrigerating machine components are not subject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammonia solution (UN2672) (see 173.307 of this subchapter). B81 Venting and pressure relief devices for tank car tanks and cargo tanks must be approved by the Associate Administrator. IBCs are only authorized if approved by the Associate Administrator. FAQ: What are Special Provisions in the USDOT/PHMSA Hazardous Materials 59 Ferrocerium, stabilized against corrosion, with a minimum iron content of 10 percent is not subject to the requirements of this subchapter. 367 For the purposes of documentation and package marking: a. 1 CFR 1.1 Date of the visual inspection must be stenciled on the tank near the other required markings. metal other than steel or aluminum (50N). (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. For all modes of transportation, a written report submitted, retained, and updated in accordance with 171.16 is required if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a dry battery or battery-powered device. Interpretation Response | PHMSA - Pipeline and Hazardous Materials Equipment powered by lithium metal batteries or lithium ion batteries must be described using the entries Lithium metal batteries contained in equipment or Lithium metal batteries packed with equipment or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment, as appropriate. The battery has been tested as a primary lithium battery; and. When chemical stabilization is employed, the person offering the material for transport shall ensure that the level of stabilization is sufficient to prevent the material as packaged from dangerous polymerization at 50 C (122 F). Each tank must be equipped with pressure relief devices conforming to the following requirements: 1 Total venting capacity in standard cubic feet hour (S.C.F.H.) Non-specification bulk bins are authorized. 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Size of marking on bulk package must conform to 172.302(b) of this subchapter. The provisions of this special provision will be effective until January 2, 2023, unless we terminate them earlier or extend them beyond that date by notice of a final rule in the Federal Register. 32 Polymeric beads and molding compounds may be made from polystyrene, poly(methyl methacrylate) or other polymeric material. For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N, of this subchapter. B47 Each tank may have a reclosing pressure relief device having a start-to-discharge pressure setting of 310 kPa (45 psig). Flammable components are flammable liquids and liquid mixtures, flammable solids and solid mixtures or flammable gases and gas mixtures meeting the following criteria: (1) A flammable liquid is a liquid having a flashpoint of not more than 93 C (200 F); (2) A flammable solid is a solid that meets the criteria in 173.124 of this subchapter; or. 118 This substance may not be transported under the provisions of Division 4.1 unless specifically authorized by the Associate Administrator (see UN0143 or UN0150 as appropriate). Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter. c. The equipment, and machinery or apparatus articles conforms with 173.222 of this subchapter. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. See 173.306(h) of this subchapter. For UN identification numbers 3531, 3532, 3533, and 3534, IBCs must be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the IBCs in the event of loss of stabilization. TP36 For material assigned this portable tank special provision, portable tanks used to transport such material may be equipped with fusible elements in the vapor space of the portable tank. 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in 173.127. Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. Different Types of Solder- All Common Classifications Note that batteries utilizing different chemistries (i.e., those battery chemistries specifically covered by another entry in the 172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent batteries in the same package. Furthermore, lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must be described using the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. For transportation of new lighter design samples for examination and testing, see 173.308(b)(2). (i) Column 8: Packaging authorizations. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. B68 Sodium must be in a molten condition when loaded and allowed to solidify before shipment. 21 This material must be stabilized by appropriate means (e.g., addition of chemical inhibitor, purging to remove oxygen) to prevent dangerous polymerization (see 173.21(f) of this subchapter). For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). The requirements of 173.24(g)(1) and 173.27(c) do not apply. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. Oxygen cylinders with installed actuating cartridges as prepared for transportation must have an effective means of preventing inadvertent activation. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. Outage must be at least 5 percent at 98 C (208 F). Packaging Authorizations (Column 8) B78 Tank cars must have a test pressure of 4.14 Bar (60 psig) or greater and conform to Class 103, 104, 105, 109, 111, 112, 114 or 120. N73 Packagings consisting of outer wooden or fiberboard boxes with inner glass, metal or other strong containers; metal or fiber drums; kegs or barrels; or strong metal cans are authorized and need not conform to the requirements of part 178 of this subchapter. 160 This entry applies to safety devices for vehicles, vessels or aircraft, e.g. (a) The Hazardous Materials Table . The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. The eCFR is displayed with paragraphs split and indented to follow Insulating materials may not promote corrosion to steel when wet. Column 4 specifies the applicability of 178.275(g)(3) of this subchapter for the pressure relief devices. 196 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). These articles must be tested in accordance with Test series 6(c) of Part I of the UN Manual of Tests and Criteria (incorporated by reference; see 171.7 of this subchapter), with no explosion of the device, no fragmentation of device casing or pressure vessel, and no projection hazard or thermal effect that would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). (ii) The following table specifies the portable tank requirements applicable to T Codes T1 through T22. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials. a. Filling limits must be in accordance with portable tank special provision TP3. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle. not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. j. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Regulation Y (v) UN and IM portable tank codes/special provisions. c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. 57 Maneb or Maneb preparations stabilized against self-heating need not be classified in Division 4.2 when it can be demonstrated by testing that a volume of 1 m3 of substance does not self-ignite and that the temperature at the center of the sample does not exceed 200 C, when the sample is maintained at a temperature of not less than 75 C 2 C for a period of 24 hours, in accordance with procedures set forth for testing self-heating materials in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). (h) Column 7: Special provisions. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent: (2) Short circuits, including but not limited to the following methods: (i) Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of non-conductive material; (ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive materials (e.g., metal) in the packagings; or, (iii) Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. B23 Tanks must be made of steel that is rubber lined or unlined. 49 U.S.C. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water. Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and. (iv) T75. meet the venting requirements in 173.24(g) or (2.) B84 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance for sulfuric acid or spent sulfuric acid in concentration up to 65.25 percent. b. Gases of Division 2.3 and gases with a subsidiary risk of 5.1 must not be used as a propellant in a chemical under pressure. This training must be documented in training records required by 172.704(d). Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. A30 Ammonium permanganate is not authorized for transportation on aircraft. 130 Batteries, dry, sealed, n.o.s., commonly referred to as dry batteries, are hermetically sealed and generally utilize metals (other than lead) and/or carbon as electrodes. b. (eg: Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation. 5101-5128, 44701; 49 CFR 1.81, 1.96 and 1.97. Radiation detectors transported as individual components must be transported as follows: (1) They must be packed in a sealed intermediate plastic liner with sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents. This content is from the eCFR and may include recent changes applied to the CFR. 365 For manufactured instruments and articles containing mercury, see UN3506. air bag inflators, air bag modules, seat-belt pretensioners, and pyromechanical devices containing Class 1 (explosive) materials or materials of other hazard classes. The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. (b) Preparation for transport. b. An installed inflation cylinder that requires recharging must be filled in accordance with 173.301(l). 6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this subchapter. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. Symbol Meaning Which is the correct column for hazardous materials? 380 For transportation by private carrier in a motor carrier only, this material is not subject to the segregation requirements of 177.848(d) of this subchapter under the following conditions: a. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. 6. Column 7: Special provisions. W10 When offered for transportation by vessel, the use of Large Packagings (see 171.8 of this subchapter) is prohibited. Examples of such vehicles are electrically-powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, trucks, locomotives, bicycles (pedal cycles with an electric motor) and other vehicles of this type (e.g., self-balancing vehicles or vehicles not equipped with at least one seating position), lawn tractors, self-propelled farming and construction equipment, boats, aircraft, wheelchairs and other mobility aids. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. 79 This entry may not be used for mixtures that meet the definition for oxidizing gas. B16 The lading must be completely covered with nitrogen, inert gas or other inert materials. Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. B52 Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. TP5 For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief system rated at a pressure not exceeding 120 percent of the portable tank's design pressure. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended. 81 Polychlorinated biphenyl items, as defined in 40 CFR 761.3, for which specification packagings are impractical, may be packaged in non-specification packagings meeting the general packaging requirements of subparts A and B of part 173 of this subchapter. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. For the regulatory description of the codes for special provisions, please refer to 49 CFR 172.102. The manufacturer must produce technical documentation of the design type, manufacture as well as the tests and their results. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. 351 Ammonium chlorate, ammonium chlorate aqueous solutions, and mixtures of a chlorate with an ammonium salt are forbidden for transport. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). c. Each glass inner packaging is protected by a means of preventing puncture of the plastic bag (e.g., sleeves or cushioning) in the event of damage to the packaging (e.g., by crushing). If you would like to comment on the current content, please use the 'Content Feedback' button below for instructions on contacting the issuing agency. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. developer resources. These mixtures may be classified in Division 4.1 when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) and approved by the Associate Administrator. A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. the hierarchy of the document. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. As a The batteries must be securely attached to the interior structure of the cargo transport unit (e.g., by means of placement in racks, cabinets, etc.) We recommend you directly contact the agency responsible for the content in question. A191 Notwithstanding the Division 6.1 subsidiary risk for this description, the toxic subsidiary risk label and the requirement to indicate the subsidiary risk on the shipping paper are not required for manufactured articles containing less than 5 kg (11 pounds) of mercury. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. This may be fulfilled by an additional locking device linked to the activator; (4) Each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (5) Each pressure receptacle must be manufactured from material which will not fragment upon rupture; (6) The design type of the article must be subjected to a fire test. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. is available with paragraph structure matching the official CFR 48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. c. Packagings are excepted from the design stress limits at elevated temperatures, as described in Section VIII of the ASME Code (IBR, see 171.7 of this subchapter). 388 a. Lithium batteries containing both primary lithium metal cells and rechargeable lithium ion cells that are not designed to be externally charged, must meet the following conditions: i. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. When used for purposes such as sterilization, inner packagings of peroxyacetic acid, stabilized, classified as UN 3107 Organic peroxide type E, liquid or UN 3109 Organic peroxide type F, liquid may be fitted with a vent consisting of hydrophobic membrane, provided: (1) Each inner packaging contains not more than 70 mL; (2) The inner packaging is designed so that the vent is not immersed in liquid in any orientation; (3) Each inner packaging is enclosed in an intermediate rigid plastic packaging with a small opening to permit release of gas and contains a buffer that neutralizes the contents of the inner packaging in the event of leakage; (4) Intermediate packagings are packed in a fiberboard box (4G) outer packaging; (5) Each outer packaging contains not more than 1.4 L of liquid; and. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. For transportation by aircraft, a telephone report in accordance with 171.15(a) is required if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a dry battery. 2 Except when authorized under Special Provision 41. 15 This entry applies to Chemical kits and First aid kits containing one or more compatible items of hazardous materials in boxes, cases, etc. Overcharge of the rechargeable lithium ion cells is precluded by design; iii. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. B13 A nonspecification cargo tank motor vehicle authorized in 173.247 of this subchapter must be at least equivalent in design and in construction to a DOT 406 cargo tank or MC 306 cargo tank (if constructed before August 31, 1995), except as follows: a. Packagings equivalent to MC 306 cargo tanks are excepted from the certification, venting, and emergency flow requirements of the MC 306 specification. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. The requirements of 173.24(g)(1) and 173.27(c) do not apply. (6) The rate of oxygen release from the outer packaging does not exceed 15 mL per hour. A2 Single packagings are not permitted on aircraft. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. 182 Equipment containing only lithium batteries must be classified as either UN 3091 or UN 3481. result, it may not include the most recent changes applied to the CFR. 9 Packaging for certain PCBs for disposal and storage is prescribed by EPA in 40 CFR 761.60 and 761.65.